ASDL-Analytical Sciences Digital Library
ASDLID 004120
           
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Added to the ASDL
2008-07-17



  General  
  Title  A Pictorial Representation of Product Operator Formalism: Non-Classical Vector Diagrams for Multidimensional NMR
  URL  http://www.biophysics.org/Portals/1/PDFs/Education...
  Annotation  This site presents a pictorial description of the product operator formalism using a non-classical vector approach. This approach allows for the representation of any arbitrary multidimensional or heteronuclear NMR experiment. A description of a complete set of 16 vector representations for weakly-coupled two-spin (I=1/2) systems is given followed by an extension of this set to three-spin systems. Finally the concepts of coherence transfer, multiple quantum spectroscopy and phase cycling are illustrated using 2D COSY, 2D INADEQUATE, DEPT and sensitivity-enhanced HSQC as examples. The content is geared to those that have some background in NMR spectroscopy, and is probably most appropriate for a graduate course in NMR. This site can be used as a teaching tool as well as by practitioners who would like to easily deconstruct a pulse sequence for a better understanding of the “spin engineering” involved.
       
  Author  Biophysical Society; Donne and Gorenstein Email  www.biophysics.org   
   
   
  Published by  Biophysical society website  
   
  Annotation Search Categories  e-texts  
  Annotation Keywords  NMR,spin physics,product - operator